Luperox TBH70X
t-Butyl Hydroperoxide
75-91-2
Arkema
North America
South and Central America
胶连\藕合\固化剂
Crosslinking / Coupling / Curing Agents
乙烯基
Vinyl
涂层
Coatings
建筑/装饰
Architectural / Decorative
汽车原始设备制造商OEM
Automotive OEM
常规工业维护
General Industrial /Maintenance
Soluble in alcohol
Soluble in ester
Soluble in ketone
Soluble in hydrocarbon
Luperox®TBH70X trtiary alkyl hydroperoxides are widely used as chemical intermediates and as free radical polymerization initiators. Tertiary hydroperoxides form free radicals.
Tertiary hydroperoxides undergo unimolecular homolysis when subjected to
heat or ultraviolet light.
Free radicals can induce the decomposition of additional hydroperoxide molecules by hydrogen abstraction.
Multivalent metals react with hydroperoxides by an oxidation-reduction
(redox) mechanism. The products formed are dependent on the metal involved and its valence. With metals such as iron, copper, cobalt and manganese, redox reactions occur with both the lower and higher valence
cations. Small amounts of metal will therefore decompose large quantities of hydroperoxide.
Used in epoxidation of olefins, formation of peroxyesters, decomposes in the presence of acid.
The decomposition products of tertiary alkyl hydroperoxides are dependent on the media in which the decomposition occurs and the decomposition temperature. The decomposition of pure (liquid phase) t-Butyl hydroperoxide and cumene hydroperoxide yields oxygen alcohol.
Tertiary alkyl hydroperoxides. Used as chemical intermediates and as free radical polymerization initiators.